The Da Hinggan Mountains are an important area in the tectonic evolution of the Central Asian Orogenic Belt (CAOB), and there are disputes over the closure time of the Paleo-Asian Ocean and the amalgamation spatiotemporal relationship between the Ergun-Hinggan Massif and the Songnun Massif. The geochronology and geochemistry of the Late Cambrian-Late Silurian volcanic rock assemblages in the ARong Qi area at the eastern margin of the Da Hinggan Mountains are studied in this paper. The results suggest that the U-Pb zircon ages of the Late Cambrian, Late Ordovician and Late Silurian volcanic rock assemblages are 507.5 ± 1.0 Ma, 456.2 ± 1.0 Ma, 446.1 ± 0.95 Ma and 423.3 ± 1.4 Ma, respectively. The Late Cambrian-Late Silurian volcanic rocks are quasi-alu-minous-peraluminous, belonging to calc-alkaline-shoshonite series, which is rich in HREE but has insignificant europium anomalies. There are abundant large ion lithophile elements (LILE) in the rock, and remarkable Nb, Ta and Ti negative anomalies. The previous data and the current study indicate that a continental margin arc tectonic setting existed in the ARong Qi-Zalantun region during the Early Paleozoic, which is inferred to be the product of the subduction-accretion-amalgama-tion of the plates along the eastern margin of the Ergun Massif during the Early Paleozoic. © 2022 by the authors. Li-censee MDPI, Basel, Switzerland.
