Reference evapotranspiration (ETo) is an effective measure of atmospheric water demand of the land surface. In-depth investigations of the relationship between ETo and primary climatic factors can facilitate the adaptable agriculture and optimize water management, especially in the ecologically fragile Taihang Mountains (THM). This work assessed the spatiotemporal dynamics of ETo and its driving climatic factors from 1973 to 2016 in THM. Results showed: (1) Annual ETo slightly increased during 1973–2016; relative humidity (RH) decreased more slowly, the temperature increased more rapidly, and wind speed (WS) decreased more rapidly at higher elevation than those at lower elevations; (2) two breakpoints occurred in ETo series at 1990 and 1997, and an “evaporation paradox” existed in 1973–1990; (3) ETo at higher elevations had greater sensitivity to changes in RH and lower sensitivity to changes in Tmax and WS. Sensitivity of ETo to minimum air temperature (Tmin) at middle elevations was lowest among three elevation bands; (4) RH and sunshine duration (SD) were the dominant climatic factors of ETo for most periods and stations. This study helps us understand the impact of climate change on ETo in mountainous areas and confirms reference evapotranspiration in high-elevation areas is particularly sensitive to climate change. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.