A squall line is a type of strongly organized mesoscale convective system that can cause severe weather disasters. Thus, it is crucial to explore the dynamic structure and hydrometeor distributions in squall lines. This study analyzed a squall line over Guangdong Province on 6 May 2016 that was observed using a Ka-band millimeter-wave cloud radar (CR) and an S-band dual-polarization radar (PR). Doppler spectral density data obtained by the CR were used to retrieve the vertical air motions and raindrop size distribution (DSD). The results showed the following: First, the CR detected detailed vertical profiles and their evolution before and during the squall line passage. In the convection time segment (segment B), heavy rain existed with a reflectivity factor exceeding 35 dBZ and a velocity spectrum width exceeding 1.3 m s−1. In the PR detection, the differential reflectivity factor (Zdr) was 1–2 dB, and the large specific differential phase (Kdp) also represented large liquid water content. In the transition and stratiform cloud time segments (segments B and C), the rain stabilized gradually, with decreasing cloud tops, stable precipitation, and a 0 °C layer bright band. Smaller Kdp values (less than 0.9) were distributed around the 0 °C layer, which may have been caused by the melting of ice crystal particles. Second, from the CR-retrieved vertical air velocity, before squall line passage, downdrafts dominated in local convection and weak updrafts existed in higher-altitude altostratus clouds. In segment B, the updraft air velocity reached more than 8 m s−1 below the 0 °C layer. From segments C to D, the updrafts changed gradually into weak and wideranging downdrafts. Third, in the comparison of DSD values retrieved at 1.5 km and DSD values on the ground, the retrieved DSD line was lower than the disdrometer, the overall magnitude of the DSD retrieved was smaller, and the difference decreased from segments C to D. The standardized intercept parameter (Nw) and shape parameter (μ) of the DSD retrieved at 1.8 km showed good agreement with the disdrometer results, and the mass-weighted mean diameter (Dm) was smaller than that on the ground, but very close to the PR-retrieved Dm result at 2 km. Therefore, comparing with the DSD retrieved at around 2 km, the overall number concentration remained unchanged and Dm got larger on the ground, possibly reflecting the process of raindrop coalescence. Lastly, the average vertical profiles of several quantities in all segments showed that, first of all, the decrease of Nw and Dm with height in segments C and D was similar, reflecting the collision effect of falling raindrops. The trends were opposite in segment B, indicating that raindrops underwent intense mixing and rapid collision and growth in this segment. Then, PR-retrieved Dm profiles can verify the rationality of the CR-retrieved Dm. Finally, a vertical velocity profile peak generated a larger Dm especially in segments C and D. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.